Experimental and computational study of metal oxide nanoparticles for the photocatalytic degradation of organic pollutants: a review

Photocatalysis is a more proficient technique that involves the breakdown or decomposition of different organic contaminants, various dyes, and harmful viruses and fungi using UV or visible light solar spectrum. Metal oxides are considered promising candidate photocatalysts owing to their low cost, efficiency, simple fabricating method, sufficient availability, and environment-friendliness for photocatalytic applications. Among metal oxides, TiO₂ is the most studied photocatalyst and is highly applied in wastewater treatment and hydrogen production. However, TiO₂ is relatively active only under ultraviolet light due to its wide bandgap, which limits its applicability because the production of ultraviolet is expensive. At present, the discovery of a photocatalyst of suitable bandgap with visible light or modification of the existing photocatalyst is becoming very attractive for photocatalysis technology. However, the major drawbacks of photocatalysts are the high recombination rate of photogenerated electron-hole pairs, the ultraviolet light activity limitations, and low surface coverage. In this review, the most commonly used synthesis method for metal oxide nanoparticles, photocatalytic applications of metal oxides, and applications and toxicity of different dyes are comprehensively highlighted. In addition, the challenges in the photocatalytic applications of metal oxides, strategies to suppress these challenges, and metal oxide studied by density functional theory for photocatalytic applications are described in detail.