Keck Planet Imager and Characterizer Emission Spectroscopy of WASP-33b

Abstract We present Keck Planet Imager and Characterizer (KPIC) high-resolution ( R ∼35,000) K -band thermal emission spectroscopy of the ultrahot Jupiter WASP-33b. The use of KPIC’s single-mode fibers greatly improves both blaze and line-spread stabilities relative to slit spectrographs, enhancing the cross-correlation detection strength. We retrieve the dayside emission spectrum with a nested-sampling pipeline, which fits for orbital parameters, the atmospheric pressure–temperature profile, and the molecular abundances. We strongly detect the thermally inverted dayside and measure mass-mixing ratios for CO ( <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" overflow="scroll"> <mml:msub> <mml:mrow> <mml:mi>logCO</mml:mi> </mml:mrow> <mml:mrow> <mml:mi>MMR</mml:mi> </mml:mrow> </mml:msub> <mml:mo>=</mml:mo> <mml:mo>−</mml:mo> <mml:msubsup> <mml:mrow> <mml:mn>1.1</mml:mn> </mml:mrow> <mml:mrow> <mml:mo>−</mml:mo> <mml:mn>0.6</mml:mn> </mml:mrow> <mml:mrow> <mml:mo>+</mml:mo> <mml:mn>0.4</mml:mn> </mml:mrow> </mml:msubsup> </mml:math> ), H 2 O ( <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" overflow="scroll"> <mml:msub> <mml:mrow> <mml:mi>logH</mml:mi> </mml:mrow> <mml:mrow> <mml:mn>2</mml:mn> </mml:mrow> </mml:msub> <mml:msub> <mml:mrow> <mml:mi mathvariant="normal">O</mml:mi> </mml:mrow> <mml:mrow> <mml:mi>MMR</mml:mi> </mml:mrow> </mml:msub> <mml:mspace width="0.25em"/> <mml:mo>=</mml:mo> <mml:mo>−</mml:mo> <mml:msubsup> <mml:mrow> <mml:mn>4.1</mml:mn> </mml:mrow> <mml:mrow> <mml:mo>−</mml:mo> <mml:mn>0.9</mml:mn> </mml:mrow> <mml:mrow> <mml:mo>+</mml:mo> <mml:mn>0.7</mml:mn> </mml:mrow> </mml:msubsup> </mml:math> ), and OH ( <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" overflow="scroll"> <mml:msub> <mml:mrow> <mml:mi>logOH</mml:mi> </mml:mrow> <mml:mrow> <mml:mi>MMR</mml:mi> </mml:mrow> </mml:msub> <mml:mo>=</mml:mo> <mml:mo>−</mml:mo> <mml:msubsup> <mml:mrow> <mml:mn>2.1</mml:mn> </mml:mrow> <mml:mrow> <mml:mo>−</mml:mo> <mml:mn>1.1</mml:mn> </mml:mrow> <mml:mrow> <mml:mo>+</mml:mo> <mml:mn>0.5</mml:mn> </mml:mrow> </mml:msubsup> </mml:math> ), suggesting near-complete dayside photodissociation of H 2 O. The retrieved abundances suggest a carbon- and possibly metal-enriched atmosphere, with a gas-phase C/O ratio of <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" overflow="scroll"> <mml:msubsup> <mml:mrow> <mml:mn>0.8</mml:mn> </mml:mrow> <mml:mrow> <mml:mo>−</mml:mo> <mml:mn>0.2</mml:mn> </mml:mrow> <mml:mrow> <mml:mo>+</mml:mo> <mml:mn>0.1</mml:mn> </mml:mrow> </mml:msubsup> </mml:math> , consistent with the accretion of high-metallicity gas near the CO 2 snow line and post-disk migration or with accretion between the soot and H 2 O snow lines. We also find tentative evidence for 12 CO/ 13 CO ∼ 50, consistent with values expected in protoplanetary disks, as well as tentative evidence for a metal-enriched atmosphere (2–15 × solar). These observations demonstrate KPIC’s ability to characterize close-in planets and the utility of KPIC’s improved instrumental stability for cross-correlation techniques.