Wood‐Derived Freestanding Carbon‐Based Electrode with Hierarchical Structure for Industrial‐Level Hydrogen Production

The sustainable and scalable fabrication of low-cost, efficient, and durable electrocatalysts that operate well at industrial-level current density is urgently needed for large-scale implementation of the water splitting to produce hydrogen. In this work, an integrated carbon electrode is constructed by encapsulating Ni nanoparticles within N-doped carbonized wood framework (Ni@NCW). Such integrated electrode with hierarchically porous structure facilitates mass transfer process for hydrogen evolution reaction (HER). Ni@NCW electrode can be employed directly as a robust electrocatalyst for HER, which affords the industrial-level current density of 1000 mA cm^-2 at low overpotential of 401 mV. The freestanding binder-free electrode exhibits extraordinary stability for 100 h. An anion exchange membrane water electrolysis (AEMWE) electrolyzer assembled with such freestanding carbon electrode requires only a lower cell voltage of 2.43 V to achieve ampere-level current of 4.0 A for hydrogen production without significant performance degradation. These advantages reveal the great potential of this strategy in designing cost-effective freestanding electrode with monometallic, bimetallic, or trimetallic species based on abundant natural wood resources for water splitting.