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In today’s world, where environmental protection and sustainability are increasingly important, it is essential to pay attention to the environmental impact of different industries. One of these industries with a potentially significant impact on life, human health, the environment, and property is gas stations, which are essential links in the fuel supply chain. This article focuses on the topic of assessing the impact of gas stations on surrounding environments and will examine the potential negative impacts that these operations can have on society and the environment. The aim of the paper is to analyze how gas stations affect their surroundings in the event of an incident involving a spill of hazardous substances. The scope of the paper is to assess the impacts of a spill of hazardous substances from a gas station, with an emphasis on assessing the risks and consequences on the life and health of the people in the immediate vicinity of the gas station. The selected gas station’s location in the High Tatras National Park enhances the study’s significance due to the unique environmental context, heightened environmental sensitivity, and potential legislative implications. ALOHA software version 5.4.7 was chosen for simulating the release of hazardous substance due to its extensive substance database, mathematical models, support for various release sources, internet availability, and graphical result representation. This manuscript argues for risk assessment beyond current legislation, addressing unclassified sources of risk. This research contributes by utilizing predictive modeling, recognizing environmental contexts, and emphasizing legislative attention. It discusses the consequences of emergency scenarios involving gasoline and LPG, addresses potential limitations and uncertainties, and advocates for accident prevention and risk assessment, especially in environmentally sensitive areas. The conclusion suggests improvements in predictive modeling, legislative adaptation, collaboration, and an expanded scope of analysis for future research. The aim of the paper is also to discuss measures that can be taken to minimize these impacts and ensure sustainable and safe operation. Assessing the risks arising from the operation of gas stations contributes to the development of measures to protect and preserve our environment for future generations.