Obsidian hydration dating by infrared transmission spectroscopy

Abstract The obsidian dating method converts the quantity of diffused molecular water within a near‐surface hydration layer to elapsed time using an experimentally derived diffusion coefficient predicted from the structural water content of the glass. Infrared spectroscopic transmission measurements on transparent archaeological samples record vibrational responses of water bands in the near‐infrared region, permitting determination of structural water content (OH), and the amount of diffused ambient water (H 2 O). In this application, the H 2 O water band at 5200 cm −1 is measured directly. The accuracy of the approach is assessed by an evaluation of the precision of each contributing variable. The new protocol is evaluated using obsidian artifacts from radiocarbon‐dated deposits at Salamanca Cave in Argentina.