ZTF SN Ia DR2: The spectral diversity of Type Ia supernovae in a volume-limited sample

More than 3000 spectroscopically confirmed Type Ia supernovae (SNe Ia) are presented in the Zwicky Transient Facility SN Ia Data Release 2 (ZTF DR2). In this paper, we detail the spectral properties of 482 SNe Ia near maximum light, up to a redshift limit of $z$ $\leq$ 0.06. We measure the velocities and pseudo-equivalent widths (pEW) of key spectral features (Si II $λ$5972 and Si II $λ$6355) and investigate the relation between the properties of the spectral features and the photometric properties from the SALT2 light-curve parameters as a function of spectroscopic sub-class. We discuss the non-negligible impact of host galaxy contamination on SN Ia spectral classifications, as well as investigate the accuracy of spectral template matching of the ZTF DR2 sample. We define a new subclass of underluminous SNe Ia (`04gs-like') that lie spectroscopically between normal SNe Ia and transitional 86G-like SNe Ia (stronger Si II $λ$5972 than normal SNe Ia but significantly weaker Ti II features than `86G-like' SNe). We model these `04gs-like' SN Ia spectra using the radiative-transfer spectral synthesis code tardis and show that cooler temperatures alone are unable to explain their spectra; some changes in elemental abundances are also required. However, the broad continuity in spectral properties seen from bright (`91T-like') to faint normal SN Ia, including the transitional and 91bg-like SNe Ia, suggests that variations within a single explosion model may be able to explain their behaviour.