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Spatial and temporal patterns of landscape Freeze/Thaw (F/T) state transitions within the cryosphere are highly variable with impacts to climate, hydrological, ecological, and biogeochemical processes. F/T state has a strong impact on the seasonal amplitude and partitioning of surface energy exchange, while ecosystem responses to seasonal thaw are rapid, with evapotranspiration, soil respiration, and plant photosynthetic activity accelerating with warmer temperatures and the availability of liquid water. The annual thaw period also influences the vegetation growing season, while variability in F/T timing rules vegetation net primary production and Net Ecosystem CO2 Exchange (NEE) with the atmosphere. More than one third of the Earth’s land surface is covered by seasonal or permanent soil frost. Many agricultural, engineering, and environmental issues and applications are affected by F/T state. A frozen land surface tends to reduce or even to impede water infiltration, which may promote flooding, surface runoff, and soil erosion.In this work, Spire data through the NASA Commercial Smallsat Data Acquisition (CSDA) Program are used to develop novel Global Navigation Satellite Systems Reflectometry (GNSS-R) methods to determine the F/T state over the Arctic-Boreal region. The generated theoretical and experimental capabilities will be applied to analyze the spatial patterns and temporal dynamics with an improved spatio-temporal sampling as compared to Synthetic Aperture Radar (SAR) missions.