High‐Performance Solution‐Processable Organic Light‐Emitting Diode Based on a Narrowband Near‐Ultraviolet Emitter and a Hot Exciton Strategy

Achieving high efficiency narrowband near-ultraviolet (NUV) emitters in organic light emitting diode (OLED) is still a formidable challenge. Herein, a proof-of-concept hybridized local and charge transfer (HLCT) molecule, named ICz-BO, is prepared and characterized, in which both multiresonant (MR) skeletons are integrated via conjugation connection. A slightly distorted structure and weak intramolecular charge transfer (CT) interaction between two MR subunits lead to a high-lying reverse intersystem crossing (h-RISC) channel of T₆→S₁, also evidenced by both experimental and calculated results. Impressively, the ICz-BO emitter exhibits outstanding narrowband NUV emission at 404 nm with a full-width at half maximum of 28 nm in toluene solution. The solution processable OLED shows an excellent device performance with the recorded maximum external quantum efficiency of 12.01 %, concomitant with an extremely low y-axis Commission Internationale de l'Éclairage (CIE_y) value of 0.031. To the best of our knowledge, this is the highest efficiency reported for the HLCT-based NUV-OLEDs to date. This research proves that the MR skeleton plays a positive effect on the narrowband hot exciton emitter, which provides an alternative paradigm for developing high-efficiency NUV emitters.