Optimizing the Effect of Nanochitosan and Kenaf Fiber on Tensile and Impact Properties of Polylactic Acid (PLA)/Natural Rubber (SMR20) Biocomposites

In this study, the influence of nanochitosan and kenaf fibers on the tensile strength, elastic modulus, and impact strength of polylactic acid (PLA)/natural rubber (Standard Malaysian Rubber, grade 20—SMR20) biocomposites was investigated experimentally using Response Surface Methodology (RSM). The independent variables included the weight percentage of nanochitosan (2, 4, and 6 wt%), kenaf fibers (5, 10, and 15 wt%), and SMR20 natural rubber (10, 20, and 30 wt%). Composite samples were prepared by melt mixing in an internal mixer and subsequently fabricated into test samples using hot compression molding in accordance with relevant standards. Tensile tests were conducted to evaluate tensile strength and elastic modulus, while Charpy impact tests were performed to assess impact strength. The results revealed that increasing nanochitosan content up to 4 wt% enhanced tensile strength, elastic modulus, and impact strength by 39%, 22%, and 27%, respectively; however, further addition (6 wt%) led to a decline in these properties due to nanoparticle agglomeration. Increasing kenaf fiber content to 15 wt% improved tensile strength, elastic modulus, and impact strength by 44%, 26%, and 37%, respectively, demonstrating their effective reinforcing role. The incorporation of SMR20 natural rubber significantly increased impact strength by 59% (at 30 wt%), while causing a reduction of 17% in tensile strength and 20% in elastic modulus, consistent with its elastomeric nature. Furthermore, field emission scanning electron microscopy (FESEM) was employed to examine the dispersion of nanochitosan and kenaf fibers within the PLA/SMR20 matrix, providing insights into the interfacial adhesion and failure mechanisms. The findings highlight the potential of optimizing natural filler and rubber content to tailor the mechanical performance of sustainable PLA-based biocomposites.