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Methane emissions from abandoned coal mining operations represent a persistent environmental and safety challenge in post-mining regions undergoing urban redevelopment. As urban infrastructure expands over former underground workings, the uncontrolled migration of mine gas can compromise public safety, exacerbate greenhouse gas emissions, and undermine sustainable development goals. This study investigates the origin of methane emissions detected in an urban area of the municipality of Lupeni, Romania, following the commissioning of a new natural gas distribution pipeline installed within a historically mined perimeter. The emissions had not been previously reported and were unexpectedly discovered during technical inspections conducted after the gas network installation, highlighting the absence of historical data on gas presence in this area. This is the first documented case of an accidental discovery of methane emissions in an urban perimeter overlying historical coal mine workings in Romania, granting this study a pioneering status, both scientifically and in terms of urban risk management. The findings emphasize that administrative mine closure does not equate to risk closure, as latent methane emissions may reactivate during urban transformations (e.g., excavations, utility upgrades, drainage changes). To ensure a scientifically sound and sustainable risk assessment, an integrated diagnostic framework was applied, combining chronological field monitoring with chromatographic gas composition analysis. This methodology enabled precise attribution of the methane source to abandoned underground mine workings, excluding the public gas network as a contributor. Based on this diagnosis, a controlled drainage and methane recovery system was implemented, resulting in the elimination of detectable concentrations at all monitoring points by February 2025. The captured methane was redirected for local energy use, transforming an environmental liability into a usable resource. This intervention supports circular economy principles and aligns with EU climate and energy transition goals. The proposed methodological framework provides a replicable model for identifying and managing residual mine gas in post-industrial urban environments. Although emission fluxes were not quantified, concentration-based screening enabled risk diagnosis, prioritization, and targeted intervention. These findings are relevant to EU Regulation (2024/1785) on methane emission reduction, emphasizing the need to include post-mining methane (AMM) in urban planning and environmental monitoring strategies. Limitations of the study include the absence of baseline data and the inability to calculate total methane flux. However, the results support immediate and practical risk mitigation and highlight the need for future work focused on long-term monitoring and emission quantification. This case provides critical insights for other post-mining cities in Central and Eastern Europe facing similar challenges at the intersection of legacy coal infrastructure and modern urban development. This study is designed as a concentration-based diagnostic and risk-oriented case study and does not aim to quantify methane emission fluxes.