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The minimisation of substances of concern in packaging is a key objective of the European Union’s Packaging and Packaging Waste Regulation (PPWR). Per- and polyfluoroalkyl substances (PFAS) present particular challenges due to their persistence, chemical diver-sity, and widespread use in food contact materials. Article 5 of the PPWR requires pack-aging to be designed and manufactured to minimise such substances throughout the life cycle. This study develops a structured, material-based PFAS risk matrix to support com-pliance screening for food packaging under Article 5. The approach combines scientific evidence on PFAS occurrence, functional applications, and analytical detection with ma-terial classification systems used in recyclability assessments. Packaging materials are categorised by their likelihood of PFAS relevance, enabling proportionate prioritisation of minimisation and documentation efforts. Application of the matrix shows that PFAS relevance is strongly material dependent. Fi-bre-based materials with grease- or water-resistant treatments exhibit higher relevance than glass, untreated paper, or polyethylene terephthalate (PET). The framework also clar-ifies the role of total fluorine (TF) and extractable organic fluorine (EOF) as supportive, material-specific indicators rather than standalone compliance metrics. By integrating PFAS considerations into design, sourcing, and portfolio management, the framework promotes proactive chemical risk governance aligned with circular economy objectives.