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This textbook module examines the intersection of cognitive neuroscience, pedagogy, and artificial intelligence as they converge in the secondary school classroom. Beginning with the theory of mental rigor — the disciplined, sustained exertion of focused cognitive effort as a biological process with measurable neural correlates — the text argues that understanding how the brain learns and understanding how AI systems learn are not separate intellectual projects but deeply connected ones. Each chapter weaves AI concepts explicitly into its treatment of the neuroscience of learning, establishing structural parallels between biological and artificial intelligence that deepen understanding of both. Chapter One presents culturally responsive classroom activities — including probabilistic choice games, biometric data analysis, memory exercises, and kinesthetic geometry — and connects each to foundational AI concepts including classification, feature engineering, sequence processing, and convolutional neural networks. Chapter Two examines learning environment design alongside AI tools for personalization, adaptive assessment, and classroom analytics, including a critical treatment of their limitations and equity implications. Chapter Three addresses the cultivation of intrinsic motivation through the lens of reinforcement learning, connecting dopaminergic reward circuitry to temporal difference learning and the exploration-exploitation tradeoff. Chapter Four provides a systematic comparison of biological and artificial neural architectures — synaptic plasticity and backpropagation, Piagetian developmental stages and inductive bias, System 1 and System 2 cognition and the symbolic-to-connectionist transition in AI. Chapter Five presents educator roundtable discussions on identity, equity, algorithmic bias, AI-era assessment, school leadership, and asset-based teaching in an AI-integrated educational landscape. The module includes a mathematical appendix connecting classroom activities to the computational foundations of machine learning, and a reference list of 32 peer-reviewed publications spanning cognitive neuroscience, educational psychology, and AI research. It is intended for educators, researchers, educational leaders, policymakers, and students engaged with the rapidly evolving relationship between human learning and artificial intelligence. This is Module 2 in the AI Topics series by Xavier Honablue, M.Ed. Module 1, Epigenetics, is available separately on Zenodo.