Comparative Analysis of Different ZnO Particles as Additives of Bio-Based Andiroba, Copaiba, and Paraffinic Mineral Oils: Effects on Lubrication Properties

The growing demand for environmentally responsible lubricants motivates the use of bio-based base stocks and benign solid additives. This study assesses the tribological performance of two Amazonian vegetable oils, Carapa guianensis (andiroba) and Copaifera spp. (copaiba resin) and a paraffinic mineral oil (PNL30) formulated with different zinc oxide (ZnO) particles, namely nanocrystals and microcrystals, at 0.01, 0.05, and 0.10 wt.%. Reciprocating sliding tests, coupled with 3D profilometry, viscosity, and sedimentation analyses, were used to link dispersion stability with friction and wear responses. A preliminary stability screening constrained the practical loading window to ≤0.10 wt.% for reproducible suspensions. Performance depended on the interplay between particle type and base-oil chemistry. Andiroba exhibited the most pronounced gains, with ZnO microcrystals near 0.05 wt.% delivering the best friction outcomes and the largest wear reductions (up to ~35%). In copaiba resin oil, nanocrystals produced small, sometimes non-significant improvements, whereas microcrystals tended to worsen wear consistent with abrasive third-body effects in a less polar matrix. In PNL30, the overall benefits were modest: nanocrystal additions generally increased wear, whereas microcrystals particularly at the highest loading 0.10 wt.% achieved a 36.4% reduction in SWR, representing a measurable and statistically significant improvement in wear resistance. These results highlight that eco-efficient lubricant design should co-optimize particle characteristics and dosage with base-oil polarity and film-forming tendencies, prioritizing dispersion stability alongside tribological targets.