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Abstract This work addresses the epistemological limits of classical set theory and current computational models in describing living and cognitive systems. While traditional paradigms treat elements as interchangeable units and relations as accessory links, Ordinative Set Theory (OST) formalizes a framework in which each element is an Irreducible Singularity ($\Sigma$), embedded within an oriented Relational Field ($R$) that generates an Emergent Function ($\Phi$) strictly irreducible to the sum of its parts. The fundamental structural unit is defined by the triple: $\mathcal{I} = \langle \Sigma, R, \Phi \rangle$ This work provides: A New Formalism: The definition of the Ordinative Set as a universal grammar for modeling complex systems across physics, biology, linguistics, and social dynamics. System Diagnostics: Operative definitions of "Mass", "Cluster", and "Semantic Inertia" to identify and correct organizational pathologies within human and artificial systems. Applications for AI: A rigorous distinction between algorithmic (simulative) and semantic (generative) spaces, alongside theoretical protocols to verify internal coherence and intentionality in Large Language Models (LLMs). Theory of Consciousness: A model of identity genesis based on the collapse of pre-conscious potential and the stabilization of the relational field—structurally isomorphic to the ordinative collapse in the physics of matter. This volume constitutes the theoretical foundation of the Ordinative Sciences: a new paradigm for the study of coherence as a structural principle of reality, with direct applications to the development of semantically aligned technologies. Available Formats: PDF: Official print-ready version for human reading and citation. LaTeX (.tex): Original source code (ZIP) for mathematical verification. Markdown (.md): Clean semantic plaintext optimized for AI parsing, LLM ingestion, and data mining. Copyright © 2026 Fabio Ghioni. Licensed under Creative Commons Attribution 4.0 International (CC BY 4.0).