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Abstract. This work presents the incorporation of a tropospheric isoprene oxidation scheme into an Earth System Model to enhance the simulation of tropospheric ozone levels. Numerical experiments were performed using two distinct model setups: one accounting for isoprene oxidation and another in which this chemical pathway was not considered.Keywords: Isoprene, tropospheric ozone, atmospheric chemistry, MIM1 mechanismUnderstanding the processes of tropospheric ozone formation is of key importance both for the development of air quality control measures and for climate prediction, especially under conditions of changing anthropogenic and biogenic emissions. While on the global scale the production of tropospheric ozone is primarily governed by the oxidation of carbon monoxide and methane, in densely populated and industrial regions non-methane volatile organic compounds (NMVOCs) become the dominant contributors. Among these NMVOCs, isoprene plays a particularly important role, with the majority of its atmospheric emissions originating from vegetation.The aim of this study is to further develop the INM RAS–RSHU chemical–climate model [1], which is a component of the Earth System Model (ESM), with an emphasis on a more accurate representation of tropospheric chemical processes. The primary focus is on the implementation of an improved chemical mechanism designed to enhance the accuracy of simulated concentrations of key atmospheric gaseous components. One of the main criteria in selecting the mechanism is achieving an optimal balance between the level of chemical detail and the computational efficiency of the model.As part of the model development, a comparative analysis of several widely used chemical mechanisms was performed, including the Mainz Isoprene Mechanism (MIM1) [2], comprising 16 species and 44 reactions; MIM2, with 69 species and 178 reactions [3]; the Model for Ozone and Related Chemical Tracers (MOZART), including 151 species and 287 reactions [4]; and the Regional Atmospheric Chemistry Mechanism (RACM), which includes more than 100 species and 363 reactions [5]. Based on the results of this analysis, the MIM1 mechanism was considered the most appropriate for initial implementation in the ESM, as it was decided to begin with the most compact option while still providing sufficient accuracy in representing key tropospheric chemical processes.To assess the impact of the MIM1 mechanism, two numerical experiments were conducted using identical model settings and boundary conditions. In the control simulation, a basic tropospheric chemistry scheme without isoprene was applied, whereas the MIM1 experiment implemented the full isoprene oxidation mechanism, including 44 chemical reactions. The study and the set of numerical experiments are aimed at optimizing the chemical component of the INM RAS–RSHU chemical–climate model in order to improve the accuracy of representing tropospheric processes while maintaining high computational efficiency. The obtained results provide a solid basis for further investigation of the interactions between chemical and dynamical processes in the atmosphere and will contribute to the development of approaches for forecasting atmospheric composition and its impact on regional and global climate change.