An Overlooked Sink: Quantifying the Impact of Aerosol Deposition on Building Walls with Large Eddy Simulation

Urban air quality is influenced by the removal of particulate matter through dry deposition, yet this process is often simplified in models, potentially underestimating the role of vertical building surfaces. This study investigates the impact of aerosol deposition on building walls on PM2.5 concentrations and the deposition budget within the urban canopy. We utilized a Large Eddy Simulation model coupled with a Lagrangian Particle Transport module to simulate aerosol dispersion in randomized urban configurations corresponding to Local Climate Zones (LCZs) 4, 5, and 6. The results indicate that under the considered conditions, vertical walls can act as a primary sink for PM2.5, capturing over 70% of deposited particles downwind from sources in high-rise environments. We observed a non-linear sensitivity of airborne concentrations to wall deposition efficiency; a relatively low capture probability (10%) reduced near-surface concentrations by 25–30%. Furthermore, for fine and coarse particles (up to ~20 µm), the uncertainty in wall deposition parameterization appeared to outweigh the influence of particle physical properties on dispersion patterns. These findings suggest that neglecting wall deposition may lead to overestimation of urban pollution levels, highlighting the importance of refining particle–wall interaction parameterizations in air quality models.