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Abstract This study presents an investigation of nearly two dozen candidate Luminous Blue Variables (cLBVs) in the galaxies M31 and M33. Eight stars have been studied in detail, while an additional sixteen objects are briefly mentioned. Multi-epoch spectra of confirmed cLBVs from LAMOST and previous literature show broad hydrogen, He I lines, abundant Fe II and [Fe II] emission lines, and discernible spectral variability, consistent with the characteristics of known LBVs. Low outflow velocities inferred from P Cygni profiles are also incorporated into the classification criteria. Moreover, key stellar properties, including temperature and luminosity, are determined using the Spectral Energy Distribution (SED) fitting and spectral modeling. By comparison with stellar evolutionary tracks on the temperatureluminosity diagram, the initial masses are estimated to be in the range of approximately 32 to 60 M⊙. Except for J013401 and J013411, other stars locate within the typical LBV region between the S Doradus instability strip and their outburst phase. More importantly, our sample, except for the binary system, are all positioned in the LBVs region rather than that of B[e]SGs in the near-infrared color-color diagram. Based on all available information, one of the eight sources is confirmed as a LBV, four stars are designated as high-probability cLBVs, and the remaining three stars await further photometric observations to secure their classification. Given the current scarcity of known cLBVs, our study has the potential to make a significant increase in the number of LBVs in M31 and M33.