Ligand-Controlled, Tunable Palladium-Catalyzed Carbonylation of Thianthrenium Salts and Formic Acids

20260 citationsJournal Articlegold Open Access

Authors

Xinyu Hu · Tianjin Normal University

Bingxiao Li · Tianjin Normal University

Hengyi Zhao · Tianjin Normal University

Ai-Ting Shi · Tianjin Normal University

Chen Chen · Tianjin Normal University

Abstract

We report a ligand-controlled palladium-catalyzed carbonylation of thianthrenium salts employing HCOOH or DCOOD as a CO source. This divergent method enables the synthesis of aromatic aldehydes, deuterated aromatic aldehydes, aromatic carboxylic acids

Topics & Keywords

Catalytic C–H Functionalization Methods Sulfur-Based Synthesis Techniques Catalytic Cross-Coupling Reactions

UN Sustainable Development Goals

Clean water and sanitation

Publication Details

DOI: 10.22541/au.177485087.75539991/v1

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