In Situ Chemical Characterization by Laser-Induced Breakdown Spectroscopy of a HFGC Tile from the JET Divertor Through In-Depth Chemical Analysis and Linear Correlation

At the end of its last experimental campaign, in December 2023, the Joint European Torus (JET) became available for testing a compact and lightweight Laser-Induced Breakdown Spectroscopy (LIBS) system to be mounted on its robotic arm. The purpose of the test was the in situ chemical characterization of its internal walls and plasma-facing components (PFCs). Among the areas measured, special attention was devoted to the PFCs of the divertor, as this area is most affected by the re-deposition of material eroded from the first wall and unburned nuclear fuel (deuterium and tritium). In this article, we present the results of the LIBS characterization of a PFC of the High Field Gap Closure (HFGC), highly subjected to these phenomena. The in-depth distribution of several ITER-relevant chemical species is discussed through in-depth and correlation analyses, and the interpretation of the results is explained in terms of erosion and re-deposition of materials from the first wall. The study allowed us to estimate the thickness of the ablated layers by each laser shot, which is on the order of a few tens of nanometers, and to outline a mapping of the thickness of the re-deposited material.