Valorization of Mineral Wool Waste as a Pozzolanic Supplementary Cementitious Material—Comparative Reactivity in Portland and Calcium Sulfoaluminate Systems

This study provides new experimental evidence indicating that powdered mineral wool waste traditionally classified as a non-reactive, non-recyclable insulation residue can function as a genuinely pozzolanic supplementary cementitious material when incorporated into Portland cement systems. Unlike previous work that has treated mineral wool exclusively as an inert filler, this research demonstrates that its amorphous silicate–aluminate phase becomes chemically active under high-alkalinity conditions. A combined experimental programme, including mechanical testing, assessment and SEM/EDS microstructural analysis, was used to evaluate replacement levels of 20%, 25%, and 40% in CEM I mortars, with CSA cement employed as a contrasting binder system. The results indicate a potential contribution of powdered mineral wool to strength development; however, this effect cannot be unequivocally attributed to pozzolanic activity alone. It may also be partially related to physical effects such as filler action and particle packing. SEM/EDS observations confirm the formation of secondary C–S–H and C–A–S–H gels, can function as a genuinely pozzolanic supplementary cementitious material. Therefore, the applied assessment approach should be treated as indicative, and further verification using complementary methods is required. This study provides new experimental evidence indicating mineral wool can potentially contribute to cementitious performance as a Supplementary Cementitious Material (SCM). However, these observations should be treated as qualitative and indicative rather than definitive proof of pozzolanic reaction. The study provides an environmentally relevant valorisation pathway for a problematic waste stream, showing that mineral wool residues containing only trace levels of immobilizable formaldehyde can be safely and effectively integrated into low-carbon binder technologies. These findings position powdered mineral wool as a previously overlooked, yet technically viable SCM, offering new opportunities for clinker reduction, waste circularity and sustainable cementitious material design.